인돌 유도체의 Pseudohalogen 화 및 Halogen 화 반응에 관한 연구(II) 인돌의 Azido 및 Thiocyanato 유도체의 새로운 합성법

• 영문명: Pseudohalogenation and Halogenation of Indole Derivativs(II)
• 발행기관: 대한약학회
• 저자명: 채동규(Dong Kyu Chae) 천문우(Moon Woo Chun) 조재천(Jae Chun Jo)
• 간행물 정보: 『약학회지』제23권 제3&4호 (1979년), 187~189쪽, 전체 3쪽
• 주제분류: 의약학 > 기타의약학
• 파일형태: PDF
• 발행일자: 1979.12.30

영문 초록

A new method for the synthesis of azido and thiocyanatoindoles by iodine and sodium azide or sodium thiocyanate in acetonitile at room temperature or 60oC was found. Azidoindoles (3-azido-3-methyl-2-phenylindolenine, 3-azido-2, 3-diphenylindolenine, 2-azidomethyl-3-methylindole and I-azido-1, 2, 3, 4-tetrahyrocarbazole) and thiocyanatoindoles(3-thiocyanatoindole, 2-phenyl-3-thiocyanato indole, 3-methyl-2-phenyl-6-thiocyanatoindole and 2, 3-diphenyl-6-thiocyanatoindole) were prepared by this method in good yields.