장쇄 알킬 질산에스테르류의 위험성 평가에 관한 연구

• 영문명: Studies on the Evaluation of Hazadous Properties for Long Chain Alkyl Nitrates
• 발행기관: 한국응용과학기술학회 (구.한국유화학회)
• 저자명: 정노희(Jeong No Hee) 남기대(Nam Ki Dae) 김홍수(Kim Hong Soo) 김태영(Kim Tae Young)
• 간행물 정보: 『한국응용과학기술학회지』한국유화학회지 제8권 제2호, 145~151쪽, 전체 7쪽
• 주제분류: 공학 > 화학공학
• 파일형태: PDF
• 발행일자: 1991.11.30

영문 초록

Hazadous properties were evaluated for Alkyl nitrates such as hexyl nitrate, decyl nitrate, dodecyl nitrate and 2-methyl pentyl nitrate, 2-hexyl ethyl nitrate. The thermochemical properties such as heat of vaporization, boiling point, flash point and kinetic parameter for aliphatic nitrate were measured to determine the hazadous properties of these compounds. The boiling points and heat of vaporization increase as the increase of alkyl chain length in alkyl nitrates. Flash point is a linear function of boiling point as same as alkanes. The rate equation in isothermal decomposition are 1/2 order and compensation effect is found between logarithm of frequency factor the activation energy, then the decomposition preceeds with similar reaction mechanism for each nitrate.

목차

ABSTRACT

I. 서론

II. 실험

III. 결과 및 고찰

IV. 결론

문헌