CLUSTER P-V CONTAINING SYSTEMS FOR THE DECREASING OF POLYMERIC MATERIAL COMBUSTION

• 영문명: CLUSTER P-V CONTAINING SYSTEMS FOR THE DECREASING OF POLYMERIC MATERIAL COMBUSTION
• 발행기관: 한국화재소방학회
• 저자명: Kodolov, V.I. Bystrov, S.G. Mikhailov, V.I. Lipanov, A.M.
• 간행물 정보: 『한국화재소방학회 학술대회논문집』1997년도 International Symposium on Fire Science and Technology, 104~111쪽, 전체 8쪽
• 주제분류: 공학 > 공학일반
• 파일형태: PDF
• 발행일자: 1997.11.30

영문 초록

Cluster systems are microcrystals of vanadiumoxided compounds such as Barium, Calcium or Sodium Metavanadates or Sodium Vanadium Bronze which are distributed into dimethyl- or diethylphosphites or microcrystals of vanadium oxides, for instance, vanadium oxide (+3), distributed into the methylphosphonic acid melted. During the interaction of vanadium compounds with the correspondent phosphororganic substances biue viscous liquids are formed. These liquids have paramagnetic properties. According to the UV and IR spectroscopic investigations as well as the results of EPR spectra the substances obtained consist of the nucleus containing 6 to 12 of vanadium atoms and the shell including ligands which are molecules of phosphites or methylphosphonic acid. Here every atom of vanadium interacts with four of phosphorus containing molecules. Sizes of the particles in these systems donot exceed 200 nm. Introduction of cluster systems (0,1 -0,3 % vanadium) into epoxy compositions before the introduction of curing agent - polyethylenepolyamine 6 -8 % leads to the acceleration of composition crosslinking and to the combustion decreasing: 1) Oxygen Index grows to 35: 2)mass losses during combustion decrease to 1-2%, 3) combustion time does not exceed 1 s; 4) the intumescence of material sample is being observed during the burner action as well as the foam coke formation.