Disruption of the Homobimetallic Anion. PPN⁺(ŋ⁵ - MeCp)Mn(CO)₂Mn(CO)₅⁻ by Ethyl Bromide

• 영문명: Disruption of the Homobimetallic Anion. PPN⁺(ŋ⁵ - MeCp)Mn(CO)₂Mn(CO)₅⁻ by Ethyl Bromide
• 발행기관: 강원대학교 기초과학연구소
• 저자명: Y. K. Park S. H. Yun D. S. Yun
• 간행물 정보: 『기초과학연구』제15집, 230~244쪽, 전체 15쪽
• 주제분류: 자연과학 > 자연과학일반
• 파일형태: PDF
• 발행일자: 2004.12.01

영문 초록

  It is widely accepted that most homobimetallic complexes show covalent character in their metal-metal bonds; however, PPN？(ŋ？ - MeCp)Mn(CO)₂Y1n(CO)？？" is likely to have a donor-acceptor metal-metal bond character as most heterobimetallic complexes have shown.   This compound was disrupted by alkyl halide in THF under a nitrogen atmosphere at various temperatures by using the pseudo first order reaction condition where on excess of ethyl bromide was employed.   This reaction is overall second order with respect to [homobimetallic complex] and [ethyl bromide].

목차

Abstract
1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions
5. Acknowledgement
6. References