1, 1’-bi-2-naphthol 환상의 인산에스테르 化合物을 利用한 아미노알코올의 光學分割

• 영문명: Optical resolution of Aminoalcohol with Active Cyclic 1,1’-bi-2-naphthol Phosphoric Acid
• 발행기관: 한국응용과학기술학회 (구.한국유화학회)
• 저자명: Park Heung Cho(朴興助) Lee Gyung Won(李京遠)
• 간행물 정보: 『한국응용과학기술학회지』한국유화학회지 제7권 제1호, 107~114쪽, 전체 8쪽
• 주제분류: 공학 > 화학공학
• 파일형태: PDF
• 발행일자: 1990.05.30

영문 초록

Optical resolution of aminoalcohols had been achived efficiently by use of (R)-2,2’-dihydroxy-1,1’-binaphtholphosphoric acid as the resolving agent in various organic solvents. Racemic aminoalcohols were resolved very easily and high enantiomer yield (about 70% e,e) in THF. On the other hand, absolute configuration of resolved aminoalcohol was (R)-configuration but one of the Valinnol and Phhenylglycinol was anti-type because of sterichindrance.Optical resolution of aminoalcohols had been achived efficiently by use of (R)-2,2’-dihydroxy-1,1’-binaphtholphosphoric acid as the resolving agent in various organic solvents. Racemic aminoalcohols were resolved very easily and high enantiomer yield (about 70% e,e) in THF. On the other hand, absolute configuration of resolved aminoalcohol was (R)-configuration but one of the Valinnol and Phhenylglycinol was anti-type because of sterichindrance.

목차

ABSTRACT

I. 序論

II. 實驗

III. 結果 및 考察

IV. 結論

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