고온석탄가스에서 황화물을 제거하기 위한 다공성 흡착제의 개발 -Ⅱ. 산화아연의 황화반응에 관한 연구-

• 영문명: Development of Porous Sorbents for Removal of Hydrogen Sulfide from Hot Coal Gas -Ⅱ. Kinetics of Suffidation on Zinc Oxide -
• 발행기관: 한국환경보건학회
• 저자명: 서인식(In Sik Seo) 이재복(Jae Bok Lee) 류경옥(Kyong Ok Yoo)
• 간행물 정보: 『1. 한국환경보건학회지』제14권 제1호, 11~22쪽, 전체 12쪽
• 주제분류: 공학 > 환경공학
• 파일형태: PDF
• 발행일자: 1988.04.30

영문 초록

Calcium oxide, lithium oxide and titanium oxide were investigated as additives of zinc oxide for the removal of hydrogen sulfide at high temperature. This experiment was performed in the range of 1.0-2.0 vol.% H₂S concentration at 623-873 K reaction temperature, using a thermogravimetric analyzer. A pore blocking model was found to fit the reaction rate and the kinetics data were sucessfully expressed by this model. The reactions between additive sorbents and hydrogen sulfide were first order with respect to hydrogen sulfide concentration in a gaseous mixture with nitrogen. Among the used sorbents, ZnO-CaO 0.5 at.% and ZnO-TiO₂ 2.0 at.% sorbents had the best additive effects on the sulfidation reaction between additive sorbents and hydrogen sulfide, whereas the ZnO-Li₂O sorbents were ineffective.

목차

Ⅰ. 서 론

Ⅱ. 실험방법

Ⅲ. 결과 및 고찰

Ⅳ. 결 론