Boron-doped Diamond 전극을 이용한 Rhodamine B와 N, N-Dimethyl-4-nitrosoanilin의 전기화학적 분해에 반응표면분석법의 적용과 공정 최적화

• 영문명: Application of the Response Surface Methodology and Process Optimization to the Electrochemical Degradation of Rhodamine B and N, N-Dimethyl-4-nitrosoanilin Using a Boron-doped Diamond Electrode
• 발행기관: 한국환경보건학회
• 저자명: 김동석(Dong-Seog Kim) 박영식(Young-Seek Park)
• 간행물 정보: 『1. 한국환경보건학회지』제36권 제4호, 313~322쪽, 전체 10쪽
• 주제분류: 공학 > 환경공학
• 파일형태: PDF
• 발행일자: 2010.08.30

영문 초록

The aim of this research was to apply experimental design methodology to optimization of conditions of electrochemical oxidation of Rhodamine B (RhB) and N, N-Dimethyl-4-nitrosoaniline (RNO, indicative of the OH radical). The reactions of electrochemical oxidation of RhB degradation were mathematically described as a function of the parameters of current (X1), NaCl dosage (X2) and pH (X3) and modeled by the use of the central composite design. The application of response surface methodology (RSM) yielded the following regression equation, which is an empirical relationship between the removal efficiency of RhB and RNO and test variables in a coded unit: RhB removal efficiency (%) = 94.21 + 7.02X1 + 10.94X2 − 16.06X3 + 3.70X1X3 +9.05X2X3 − 3.46X12− 4.67X2 2− 7.09X32; RNO removal efficiency (%) = 54.78 + 13.33X1 + 14.93X2− 16.90X3. The model predictions agreed well with the experimentally observed result. Graphical response surface and contour plots were used to locate the optimum point. The estimated ridge of maximum response and optimal conditions for the RhB degradation using canonical analysis was 100.0% (current, 0.80 A; NaCl dosage, 2.97% and pH 6.37).

키워드

response surface methodology(RSM) electrochemical oxidation central composite design(CCD) analysis of variance(ANOVA) dye RNO